The Cloud Ice Mountain Experiment (CIME) 1998: experiment overview and modelling of the microphysical processes during the seeding by isentropic gas expansion     

Wolfram Wobrock  Andrea I. Flossmann  Marie Monier  Jean-Marc Pichon  Laurent Cortez  Jean-Franois Fournol  Alfons Schwarzenbck  Stephan Mertes  Jost Heintzenberg  Paolo Laj  Giordano Orsi  Loretta Ricci  Sandro Fuzzi  Harry Ten Brink  Piet Jongejan  Ren Otjes 《Atmospheric Research》2001,58(4):7907

The second field campaign of the Cloud Ice Mountain Experiment (CIME) project took place in February 1998 on the mountain Puy de Dôme in the centre of France. The content of residual aerosol particles, of H₂O₂ and NH₃ in cloud droplets was evaluated by evaporating the drops larger than 5 μm in a Counterflow Virtual Impactor (CVI) and by measuring the residual particle concentration and the released gas content. The same trace species were studied behind a round jet impactor for the complementary interstitial aerosol particles smaller than 5 μm diameter. In a second step of experiments, the ambient supercooled cloud was converted to a mixed phase cloud by seeding the cloud with ice particles by the gas release from pressurised gas bottles. A comparison between the physical and chemical characteristics of liquid drops and ice particles allows a study of the fate of the trace constituents during the presence of ice crystals in the cloud.In the present paper, an overview is given of the CIME 98 experiment and the instrumentation deployed. The meteorological situation during the experiment was analysed with the help of a cloud scale model. The microphysics processes and the behaviour of the scavenged aerosol particles before and during seeding are analysed with the detailed microphysical model ExMix. The simulation results agreed well with the observations and confirmed the assumption that the Bergeron–Findeisen process was dominating during seeding and was influencing the partitioning of aerosol particles between drops and ice crystals. The results of the CIME 98 experiment give an insight on microphysical changes, redistribution of aerosol particles and cloud chemistry during the Bergeron–Findeisen process when acting also in natural clouds.  相似文献   

Behaviour of H₂O₂, NH₃, and black carbon in mixed-phase clouds during CIME     

Paolo Laj  Andrea I. Flossmann  Wolfram Wobrock  Sandro Fuzzi  Giordano Orsi  Loretta Ricci  Stephan Mertes  Alfons Schwarzenbck  Jost Heintzenberg  Harry Ten Brink 《Atmospheric Research》2001,58(4):256

We investigated the partitioning of trace substances during the phase transition from supercooled to mixed-phase cloud induced by artificial seeding. Simultaneous determination of the concentrations of H₂O₂, NH₃ and black carbon (BC) in both condensed and interstitial phases with high time resolution showed that the three species undergo different behaviour in the presence of a mixture of ice crystals and supercooled droplets. Both H₂O₂ and NH₃ are efficiently scavenged by growing ice crystals, whereas BC stayed predominantly in the interstitial phase. In addition, the scavenging of H₂O₂ is driven by co-condensation with water vapour onto ice crystals while NH₃ uptake into the ice phase is more efficient than co-condensation alone. The high solubility of NH₄⁺ in the ice could explain this result. Finally, it appears that the H₂O₂–SO₂ reaction is very slow in the ice phase with respect to the liquid phase. Our results are directly applicable for clouds undergoing limited riming.  相似文献   

A clinopyroxene geobarometer for basaltic systems based on crystal-structure modeling   总被引：9，自引：0，他引：9  

Paolo Nimis 《Contributions to Mineralogy and Petrology》1995,121(2):115-125

 The crystal chemical response of basalt clinopyroxene to increasing pressure was investigated by means of crystal-structure simulation (a procedure that enables modeling of the structural parameters of a clinopyroxene of known chemistry without requiring direct X-ray diffraction analysis) using available experimental chemical data. Pressure proved the main physical variable governing clinopyroxene behavior in a magmatic environment. The general internal consistency of the simulation data permitted construction of an empirical geobarometer based on the relationship of cell volume (Vc) vs M1-site volume (VM1). The straightforward geobarometric formulation in the absence of direct X-ray analysis is: P(kbar)=698.443+4.985⋅Al_T−26.826⋅Fe²⁺ _M1−3.764⋅Fe³⁺ +53.989⋅Al_M1+3.948⋅Ti+14.651⋅Cr −700.431⋅Ca−666.629⋅Na−682.848⋅Mg_M2−691.138⋅Fe²⁺ _M2−688.384⋅Mn−6.267⋅(Mg_M2)²−4.144⋅(Fe²⁺ _M2 where: (Fe²⁺ _M1⋅Mg_M2)/(Fe²⁺ _M2⋅Mg_M1)=e^**(0.238⋅R³⁺+0.289⋅CNM−2.315), CNM=Ca+Na+Mn, and R³⁺=Al_M1+Fe³⁺+Ti+Cr, with cations in atoms per formula unit. The geobarometer reproduces experimental pressures within ±2 kbar (=1σ; max. dev. ≤5 kbar; N=29) in the range 0–24 kbar and is applicable to near-liquidus C2/c clinopyroxenes crystallized from basaltic melts in the absence of garnet (excepting high-Al₂O₃ basalts). It is therefore suitable for many natural clinopyroxenes occurring as mega- or phenocrysts or forming well-preserved cumulate pyroxenites. If the above restrictions are not wholly satisfied, the Vc vs VM1 plot can also be used qualitatively to deduce the relative pressure conditions of clinopyroxenes forming from similar batches of magma. The structural simulation of experimental data also provided insight into the influence of minor chemical changes of the parental magma on the crystal chemistry of clinopyroxene at high pressure. Within the considered compositional space at given P-T, a _CaO and a _SiO2 in the melt have opposite effects on M2- and T-site cation populations. As a result, under similar physical conditions, clinopyroxenes from higher-CaO or more undersaturated basalts have higher VM2, VT and Vc and lower VM1. For basalts with normal contents of Al₂O₃ (<18 wt %), variations of major elements in the melt do not reduce the accuracy of the geobarometer. Received: 3 April 1994 / Accepted: 23 December 1995  相似文献   

A case of no-wind plinian fallout at Pululagua caldera (Ecuador): implications for models of clast dispersal     

Paolo Papale  Mauro Rosi 《Bulletin of Volcanology》1993,55(7):523-535

The caldera of Pululagua is an eruptive centre of the Northern Volcanic Zone of the South American volcanic arc, located about 15 km north of Quito, Ecuador. Activity leading to formation of the caldera occurred about 2450 b.p. as a series of volcanic episodes during which an estimated 5–6 km³ (DRE) of hornblende-bearing dacitic magma was erupted. A basal pumice-fall deposit covers more than 2.2x10⁴ km² with a volume of about 1.1 km³ and represents the principal and best-preserved plinian layer. Circular patterns of isopachs and pumice, lithic and Md isopleths of the Basal Fallout (BF) around the caldera indicate emplacement in wind-free conditions. Absence of wind is confirmed by an ubiquitous, normally graded, thin ash bed at the top of the lapilli layer which originated from slow settling of fines after cessation of the plinian column (co-plinian ash). The unusual atmospheric conditions during deposition make the BF deposit particularly suitable for the application and evaluation of pyroclast dispersal models. Application of the Carey and Sparks' (1986) model shows that whereas the 3.2-, 1.6-, and 0.8-cm lithic isopleths predict a model column height of about 36 km, the 6.4-cm isopleth yields and estimate of only 21 km. The 4.9- and 6.4-cm isopleths yield a column height of 28 km using the model of Wilson and Walker (1987). The two models give the same mass discharge rate of 2x10⁸ kg s^-1. A simple exponential decrease of thickness with distance, as proposed by Pyle (1989) for plinian falls, fits well with the BF. Exponential decrease of size with distance is followed by clasts less than about 3 cm, suggesting, in agreement with Wilson and Walker (1987), that only a small proportion of large clasts reach the top of the column. Variations with distance in clast distribution patterns imply that, in order to obtain column heights by clast dispersal models, the distribution should be known from both proximal and distal zones. Knowledge of only a few isopleths, irrespective of their distance from the vent, is not sufficient as seemed justified by the method of Pyle (1989).  相似文献   

Minutes of the work of the Meetings of the Section of Levelling     

Paolo Dore  O. Simonsen 《Journal of Geodesy》1959,33(2):1-5

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Certain particular solutions of the clairaut equation     

Paolo Lanzano 《Astrophysics and Space Science》1973,20(1):71-83

A study has been conducted to ascertain conditions on the density distribution within a fluid, rotating planet in order that the deformation of its outer shell be expressible in terms of the Bessel functions of the first kind and the Gaussian hypergeometric series.It has been established that (1) the density must be a solution to an ordinary differential equation of the Riccati type, and (2) two already considered density distributions are the only closed-form solutions of physical relevance.  相似文献   

Sopra una clorite (penninite) della valle del Dragone nell'appennino emiliano     

Paolo Gallitelli 《Mineralogy and Petrology》1954,4(1-4):283-287

Riassunto Viene descritta una penninite di Boccassuolo nell'Appennino modenese, e attraverso lo studio ottico, chimico, roentgenografico e termico differenziale ne vengono definite le proprietà caratteristiche. L'esame della curva termico differenziale e degli spettrogrammi Debye ottenuti da polvere di penninite scaldata fra 900° e 950° permette di stabilire che la trasformazione penninite-enstatite inizia già nell'ambito di temperatura compreso fra 910° e 940°.Con 1 figura.  相似文献   

Effects of trace metal and exposure to air on serotonin and dopamine levels in tissues of the mussel Perna perna   总被引：1，自引：0，他引：1  

Almeida EA  Bainy AC  Medeiros MH  Di Mascio P 《Marine pollution bulletin》2003,46(11):1485-1490

We evaluated levels of serotonin (5HT) and dopamine (DOPA) in muscle and digestive glands of the mussel, Perna perna, collected at different times of day; exposed to air for 24 h, followed by re-submersion; and after exposure to different metals. Mussels collected at different periods of day showed little oscillation in 5HT and DOPA levels. Mussels exposed to metals showed significant changes in 5HT and DOPA levels in digestive gland and muscle, as did mussels exposed to air. Our data suggest that analyses of 5HT and DOPA in tissues of mussels could serve as a tool to evaluate the presence and effects of heavy metal contamination in mussels. Care in data interpretation is required, however, since other environmental factors such as exposure of mussels to air (i.e. at low tides) can also cause changes in DOPA and 5HT levels. Additional research is necessary to separate such natural environmental effects from effects of contaminants.  相似文献   

Migrating sand waves     

Giovanni?BesioEmail author  Paolo?Blondeaux  Maurifio?Brocchini  Giovanna?Vittori 《Ocean Dynamics》2003,53(3):232-238

A simple mathematical model is described, which reproduces the major features of sand waves' appearance and growth and in particular predicts their migration speed. The model is based on the linear stability analysis of the flat configuration of the sea bottom subject to tidal currents. Attention is focused on the prediction of the complex growth rate that bottom perturbations undergo because of both oscillatory fluid motions and residual currents. While the real part _r of controls the amplification or decay of the amplitude of the bedforms, the imaginary part _i is related to their migration speed. Previous works on the migration of the sand waves (Németh etal. 2002) consider a forcing tide made up by the M2 constituent (oscillatory period equal to 12 h) plus the residual current Z0 and predict always a downcurrent migration of the bedforms. However, field cases exist of upcurrent-migrating sand waves (downcurrent/upcurrent-migrating sand waves mean bedforms moving in the direction of the steady residual tidal current or in the opposite direction, respectively). The inclusion of a tide constituent characterized by a period of 6 h (M4) is the main novelty of the present work, which allows for the prediction of the migration of sand waves against the residual current Z0. Indeed, the M4 tide constituent, as does also the residual current Z0, breaks the symmetry of the problem forced only by the M2 tide constituent, and induces sand-wave migration. The model proposed by Besio etal. (2003a) forms the basis for the present analysis. Previous works on the subject (Gerkema 2000; Hulscher 1996a,b; Komarova and Hulscher 2000) are thus improved by using a new solution procedure (Besio etal. 2003a) which allows for a more accurate evaluation of the growth rate for arbitrary values of the parameter r, which is the ratio between the horizontal tidal excursion and the perturbation wavelength. Responsible Editor: Jens Kappenberg  相似文献   

Improvement of Nakamura technique by singular spectrum analysis   总被引：1，自引：1，他引：1  

Roberto Carniel  Fausto Barazza  Paolo Pascolo 《Soil Dynamics and Earthquake Engineering》2006,26(1):55-63

In this work we investigate the application of the Singular Spectrum Analysis to improve Nakamura Technique. The SSA has a wide and multidisciplinary range of applications; it allows a time series to be decomposed into different components, e.g. the signal itself, as well as various noise components, which can be subsequently removed from the data. Removal of the minor component of the data can lead to significant improvements in the identification of the system. In this paper the use of SSA Technique allows to optimize the signal to noise ratio before computing the classical Nakamura spectral ratios. A number of typical applications are also presented.  相似文献